Selasa, 22 Mei 2018

Sponsored Links

SURFACTANTS. - ppt video online download
src: slideplayer.com

Alkylbenzene sulfonates are a class of anionic surfactants, consisting of a hydrophilic sulfonate head-group and a hydrophobic alkylbenzene tail-group. Along with SLES they are one of the oldest and most widely used synthetic detergents and may be found in numerous personal-care products (soaps, shampoos, toothpaste etc.) and household-care products (laundry detergent, dishwashing liquid, spray cleaner etc.). They were first introduced in the 1930s in the form of branched alkylbenzene sulphonates (BAS) however following environmental concerns these were replaced with linear alkylbenzene sulphonates (LAS) during the 1960s. Since then production has increased significantly from about 1 million tons in 1980, to around 3.5 million tons in 2016, making them most produced anionic surfactant after soaps.


Video Alkylbenzene sulfonates



Branched alkylbenzene sulfonates (BAS)

Branched alkylbenzene sulfonates were first introduced in the early 1930's and saw significant growth from the later 1940's onwards, in early literature these synthetic detergents are often abbreviated as syndets. They were prepared by the Friedel-Crafts alkylation of benzene with 'propylene tetramer' followed by sulfonation. Propylene tetramer being a broad term for a mixture of compounds formed by the oligomerization of propene, its use gave a mixture of highly branched structures.

Compared to traditional soaps BAS offered superior tolerance to hard water and better foaming. However, the highly branched tail made it difficult to biodegrade. BAS was widely blamed for the formation of large expanses of stable foam in areas of wastewater discharge such as lakes, rivers and costal areas (sea foams), as well as foaming problems encountered in sewage treatment and contamination of drinking water. As such BAS was phased out of most detergent products during the 1960s, being replaced with linear alkylbenzene sulfonates (LAS). It is still important in certain agrochemical and industrial applications, where rapid biodegradability is of reduced importance.


Maps Alkylbenzene sulfonates



Linear alkylbenzene sulfonates (LAS)

LAS is prepared industrially by the sulfonation of linear alkylbenzenes (LABs), which can be prepared in several ways. In the most common route benzene is alkylated by long chain monoalkenes (e.g. dodecene) using hydrogen fluoride as a catalyst. The purified dodecylbenzenes (and related derivatives) are then sulfonated with sulfur trioxide to give the sulfonic acid. The sulfonic acid is subsequently neutralized with sodium hydroxide. The term linear refers to the starting alkenes rather than the final product. The alkylation of linear alkenes, even 1- alkenes such as 1-dodecene gives several isomers of phenyldodecane.


Frontiers | The role of bacteria and mycorrhiza in plant sulfur ...
src: www.frontiersin.org


Structure property relationships

Under ideal conditions the cleaning power of BAS and LAS is very similar, however LAS performs slightly better in normal use conditions, due to it being less effected by hard water. Within LAS itself the detergency of the various isomers are fairly similar, however their physical properties (Krafft point, foaming etc.) are noticeably different. In particular the Krafft point of the high 2-phenyl product remains below 0°C up to 25% LAS whereas the low 2-phenyl cloud point is ~15°C. This behavior is often exploited by producers to create either clear or cloudy products.


Biomass--The next revolution in surfactants?
src: www.aocs.org


Environmental fate

Biodegradability has been well studied, and is affected by the isomerization (branching). The salt of the linear material has an LD50 of 2.3 mg/liter for fish, about 4x more toxic than the branched compound; however the linear compound biodegrades far more quickly, making it the safer choice over time. It is biodegraded rapidly under aerobic conditions with a half-life of approximately 1-3 weeks; oxidative degradation initiates at the alkyl chain. Under anaerobic conditions it degrades very slowly or not at all, causing it to exist in high concentrations in sewage sludge, but this is not thought to be a cause for concern as it will rapidly degrade once returned to an oxygenated environment.


Biomass--The next revolution in surfactants?
src: www.aocs.org


References

Source of the article : Wikipedia

Comments
0 Comments